I was able to do this successfully and upload onto our LMS. It may seem silly but double check that when you link your button to open a pdf, the file name needs to be just the name of the pdf (no file path). Then you put that pdf into the unzipped published folder. The only thing I noticed is that by default it does open the PDF in the same window as the captivate project, so unless the user were to use the browser back button they could not go back to the course. I haven't explored how to get it to open in a new window yet.
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